2017年8月17日星期四

Cooling Water Therapy

Corrosion is considered one of the main issues encountered in cooling water remedy. Many cooling programs are made from ferrous metal components and two basic problems can result if corrosion is just not controlled:
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a) Failure of gear leading to unscheduled downtime, loss of production and price of replacements;
b) Decrease in plant effectivity because of deposition of corrosion merchandise in heat exchangers leading to a loss of heat switch.
The corrosive potential of a system will be predicted from water analyses and the Langelier or Ryznar indices; empirical instruments for predicting scale and corrosive tendencies of pure waters primarily based on their chemical analyses and the thermodynamic constants for CO2/H2O/CaCO3 system. A calculation is manufactured from the theoretical pH (pHs) at which a specific water is just in equilibrium with calcium carbonate. Predictions are then made based on the precise water pHa.
(pHs = (pK2 – pKs) + pCa2 + pAlk )
Langelier Index = pHa – pHs if optimistic this signifies scale forming, if detrimental then corrosive.
Ryznar Index = 2pHs – pHa
four – 5 Heavy scale
5 – 6 Slight scale
6 – 7 Scale / Corrosion
7 – 7.5 Corrosive
7.5 – 9 Highly corrosive
Safety from corrosion might be achieved both by altering the steel or the setting. Altering the steel is costly and will not all the time achieve success. Changing the surroundings is a broadly used, sensible methodology to control corrosion. In cooling programs two practical approaches could also be adopted: a) Use the natural calcium and alkalinity within the water to type a protecting calcium carbonate layer on the surface;
b) Add corrosion inhibitors.
Neither approach is unique and the choice of therapy might be primarily based on an analysis of system requirements and corrosion control required. Most techniques at the moment function at what known as “natural pH”. That is the pH to which the system rises on the operating focus factor and is normally in the rage eight to 9. This may result in reduced corrosion charges however there may be nonetheless the necessity for added corrosion inhibitor to achieve satisfactory corrosion charges
Scale Formation The most generally occurring scale forming chemical is calcium carbonate (CaCO3). Other common scale forming chemicals are calcium sulphate (CaSO4) and calcium phosphate (Ca3(PO4)2. These and other less widespread chemicals that may kind scales such as iron oxides, silica (and silicates) have one property in frequent – they are both solely very barely soluble or exhibit inverse solubility characteristics, i.e. they turn out to be much less soluble with rising water temperature.
Scale formation reduces the ability of the metal to conduct heat effectively and results in a discount within the efficiency of the system.
Scale management may be achieved in three ways:
1. by operating the system in a non scaling approach ( Langelier / Ryznar assist define this);
2. by eradicating some or all the calcium utilizing a water softener;
Three. by modifying the precipitation of the size with inhibitors in order that it’s non-scale forming.
Once more these approaches should not mutually unique and therapy is commonly a combination of all three Microbial Fouling
The water in a cooling water treatment system provides a favourable surroundings for the expansion of micro-organisms. Microbial progress on surfaces can result in the development of biofilms. If uncontrolled, such movies can cause fouling which might:
scale back the efficiency of equipment;
promote scale formation and steel corrosion;
create a reservoir of undesirable organisms reminiscent of legionella.
Microbial control is most often achieved by the addition of oxidising biocides (either chlorine or bromine) as the prime biocidal therapy which may be complemented by speciality natural biocides and biodispersants.
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Deposition Fouling Issues
Deposition, as in comparison with scale formation, occurs when insoluble particulates within the circulating water adhere to surfaces. Deposition might be a selected downside when circulate velocities are low or there are dead ends. Particulate deposition will be the precursor for scale, corrosion and biofilm formation.
Most particulates, equivalent to clay or silt, enter a system with the make-up water. Different sources are by airborne contamination being scrubbed out in the tower (corrosion merchandise from inner corrosion) aluminum and iron hydroxides can enter a system from poorly operated pre-treatment plant.
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